This single is available in this CD collection: Singles 6: 1969-1970. Also in this MP3 collection: The Singles Volume Six: 1969-1970. Some bouncy soul-funkiness from the inventor of FUNK, James Brown!
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Poster on YouTube says that this is from the first episode of a show called The Music Scene. The show was hosted by David Steinberg who eventually got his own talk show a few years later. Groovy was in full effect here obviously.